MTV, in the home stretch of planning for Sunday’s 2009 Movie Awards, has announced another group of presenters for the show, including Chris Pine, Kiefer Sutherland and the Sacha Baron Cohen character Brüno.

Also joining the list are Leann Rimes, Ed Helms, Anna Faris, Justin Bartha and Triumph the Insult Comic Dog, MTV tells PEOPLE exclusively Thursday. Other stars, announced earlier this month, who will bequeath the Golden Popcorn trophies include Will Ferrell, Cameron Diaz, Vanessa Hudgens, Ryan Reynolds, Denzel Washington, Leighton Meester, Jonah Hill and Lil Wayne.

The show is being hosted by Saturday Night Live funnyman Andy Samberg. Eminem and Kings of Leon are among the musical performers scheduled to appear.

Twilight leads the film hopefuls with seven nominations, including best movie, best female performance (Kristen Stewart) and male breakthrough performance (both Robert Pattinson and Taylor Lautner). Slumdog Millionaire earned six nominations, including best movie, female breakthrough performance (Freida Pinto) and male breakthrough performance (Dev Patel).

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